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Sulfuric acid can be manufactured by several processes including the burning of pure sulfur, roasting of pyrite and from the recovery of SO 2 stack gas from a smelter operation. Combustion may produce carbon and sulfur oxides. Material Safety Data Sheet Sulphuric acid MSDS Section 1: Chemical Product and Company Identification Product Name: Sulphuric acid Catalog Codes: 11760, 21760 CAS#: 7664-93-9 RTECS: WS5600000 TSCA: TSCA 8(b) inventory: Sulphuric acid CI#: Not applicable. Biochemical oxygen demand (BOD) It is soluble in water with release of heat. Precautionary statement(s ) P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. 0000004364 00000 n Multi-purpose sulfuric acid standard solution. REGULATORY INFORMATION . Persistence and degradability Sulfuric Acid, 5.0N (2.5M) Persistence and degradability Not established. x�b```���\�� cc`a�����д���ہ�AG@����W��f�ԏ]Ƞ�I���~K� ۘ[����'ǂ�2��^� J�l. 0000001466 00000 n ... strong-inorganic-acid mists containing sulfuric acid is carcinogenic to humans (group 1). 0000076620 00000 n US DOT UN2796, Sulfuric acid solution, 8, pg II TDG UN2796, SULFURIC ACID SOLUTION, 8, PG II IMDG UN2796, SULFURIC ACID SOLUTION, 8, PG II Marine Pollutant No IATA/ICAO UN2796, Sulfuric acid solution, 8, pg II . Specific Gravity 1.49 g/mL @ 20°C. MSDS Name:Sulfuric acid 90-98%. %%EOF SAFETY DATA SHEET: SULFURIC ACID, 50% SULFURIC ACID, 50% S979.10; S979.32; S978.8S INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800-424-9300 (Outside USA 703-527-3887) 1216 6th Ave N Kent WA 98032 Phone: 253-479-7000 Sulfuric acid is a colorless to amber, slightly cloudy and oily liquid with a specific gravity of 1.84 at 95% strength. Incompatible Materials Water, Organic materials, Strong acids, Strong bases, Metals, Alcohols, Cyanides, Sulfides Hazardous Decomposition ProductsSulfur oxides, Hydrogen Hazardous Polymerization Hazardous polymerization does not occur. 1 0 obj 42 0 obj <> endobj High levels of acid mist are also irritating to the skin and eyes. stream 0000004062 00000 n Molecular weight 98.08.. Section 1 - Chemical Product and Company Identification. Sulfuric Acid 93% Safety Data Sheet (SDS) Health 3 Fire 0 Reactivity 0 Personal Protection 3 0 Section 1: Chemical Product and Company Identification Product Name: Sulfuric Acid 93% CAS#: 7664-93-9 Synonym: Oil of Vitriol; Sulfuric Acid Chemical Name: Hydrogen sulfate Chemical Formula: H2-SO4 Contact Information: 0000002931 00000 n Box 191 Chemtrec: (800)424-9300 Kilgore, Texas 75663 1-800-256-6644. Sulfuric acid is a clear, colorless and odorless liquid. Section 1 - Chemical Product and Company Identification. 0000004097 00000 n strong inorganic acid mists containing sulfuric acid is carcinogenic to man, causing cancer of the larynx and, to a lesser extent, the lung. 0000073911 00000 n endobj 0000010838 00000 n Sulfuric acid 90-98% ACC# 22350. 9|��^T�#N���oR�~���C���F�8 �ׄ|(�w,��k���(^/����� ���,Sz�ރO��2��_����|������x�|y�ى4�0��a��T� Ӵ�?������,l�_v08��I�L�����4[v(b��1�i���W�m$e����M�R�����l�?����D�*��(Ϳ������C�9*��vB�N���3. 1.2. 0000065982 00000 n trailer Product: Sulfuric Acid, 50% v/v; 96% w/w Revision Date: 05/19/2016 6/7 Carcinogenic Effects: This product may cause cancer. 0000001676 00000 n Sulfuric Acid - MSDS. Material Safety Data Sheet SULPHURIC ACID 98% Issue Date: 01-Sep-2014 Version No: 3.0 Page 1 of 6 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME SULPHURIC ACID 98% STATEMENT OF HAZARDOUS NATURE Considered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms legislation. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should not be repeated for more than 4 times per day. <> Appearance Clear, colorless liquid. Sulfuric acid is not listed as a carcinogen by OSHA, NTP, IARC, ACGIH or the EU. 0000003233 00000 n It will char wood and most other organic matter on contact, but is unlikely to cause a fire. Exposure to moist air or water. 0000002775 00000 n 0000008145 00000 n Sulfuric acid 95-97% MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. I���D��>|��3n��|�3���O�}8�ӫ�Ӷ�m�kGl:H�|]�ǘ�!�� ��Sv���Q0��-o�Bv,�&��[p�Àf�a���>6��p�-�F+��mۍ��h�;�tf,�/$t�g��p�>L�G�ȧ�;�>�^���;��C�,��6j���: ���7/n�J]�N����X�qv:ݔ���gg��>7ή҃X'U��\���݈��������� �W��wR#$�����Q���������5�7��f1d�����Lv��M��f#�P:_v�3����6r���T�mn5��:�L��>���o^��|�{��0�`������{G�O�|�kCW������������Q�Vov. Sulphuric Acid CAS No 7664-93-9 MATERIAL SAFETY DATA SHEET SDS/MSDS. 0000076881 00000 n 0000061843 00000 n SULFURIC ACID 93.00 ( TWA ) 1 mg/m3 ( TWA ) 1 mg/m3 7664-93-9 Note - Sulfuric Acid is listed on the SARA Title III toxic 313 list III. Direct eye contact can result in blindness. Sulfuric Acid 1August 2009. 0000007882 00000 n TSCA Inventory Status All ingredients are listed on the TSCA inventory. 42 29 4.2 Most important symptoms and effects, both acute and delayed 4.3 Immediate medical attention and special treatment needed CORROSIVEPOISONINGTREATMENT:Immediatetreatmentpreferablyinahospitalismandatory.Intreatingcorrosivepoisoning, RISK: Sulfuric acid is very irritating and corrosive to the skin, eyes, respiratory track and gastrointestinal track. >> Extremely corrosive - Causes severe burns - Reacts violently to water. Items with this mark may be considered hazardous under some shipping conditions. : 7664-93-9 Product code : LC25550 Formula : H2SO4 Synonyms : battery acid / brown acid / brown oil of vitriol / dihydrogen sulfate / dipping acid / electrolyte acid / nordhausen acid / oil of vitriol / sulphuric acid . Lung damage, chronic bronchitis. 0000001255 00000 n ADVANCED SEARCH. High levels of acid mist are also irritating to the skin and eyes. 0000007723 00000 n Aldrich-339741; Sulfuric acid 0.99999; CAS Number: 7664-93-9; Linear Formula: H2SO4; find related products, papers, technical documents, MSDS & more at Sigma-Aldrich. xref Sulfuric acid and other mineral acids mist statement The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists containing sulfuric acid" as a known human carcinogen, (IARC category 1). Show this Safety Data Sheet to the medical personnel. Material Safety Data Sheet Sulfuric acid 90-98%. )�]A�g�q�ې�_�(7���4ʃ�� ���L_8��{㛡�2 ��Ǩb�ԩ2���� PRODUCT AND COMPANY IDENTIFICATION Product Name: Sulfuric Acid 35% Synonyms/Generic Names: Battery Acid, Dihydrogen Sulfate, Oil of Vitriol Product Number: 9705 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. N4335 Temkin Rd. Excess heat. 70 0 obj <>stream Sulfuric Acid (Certified ACS Plus) Revision Date 06-Jul-2018 Conditions to Avoid Incompatible products. 0000000876 00000 n Material Safety Data Sheet Version 5.2 Revision Date 11/20/2013 Print Date 03/20/2014 1. << Hazard Information Emergency Overview: - Danger! Description of first aid measures General information Get medical attention immediately. Shortness of breath. %���� 100 mL Marked Dropping Bottle Hazardous Items. Density 15 lb / gal. 0000004873 00000 n Sulfuric acid 99.999 % | 7664-93-9 | Sigma-Aldrich. Ingestion of sulfuric acid can burn the mouth and throat, and erode the stomach; death can occur. 0000000016 00000 n Revised on 12/13/2016 Page 1 of 6 Safety Data Sheet Sulfuric Acid 35% 1. The corresponding STEL level is 3 mg/m³. 0000003607 00000 n Sulfuric acid 3 1 A time weighted average (TWA) has been established for Sulphuric acid (Safe Work Australia) of 1 mg/m³. Odor Very slight odor. X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? Recommended use and restrictions on use 77, No. If necessary, we will change your selected shipping method to accomodate these items. Coughing. %PDF-1.4 Sulfuric acid may react with most metals, especially when dilute, to produce extremely flammable and potentially explosive hydrogen gas which can form explosive mixtures with air. Damage to teeth and %PDF-1.4 %���� Contact with metals may form hydrogen gas which is flammable and can result in explosion. MATERIAL SAFETY DATA SHEET - MSDS Sulfuric Acid (Concentrated) Martin Product Sales, LLC Emergency Assistance P.O. mists containing sulphuric acid is classified as carcinogenic to humans (IARC Group 1). Product containers can melt in the heat of a fire. Inhalation of sulfuric acid mist or fumes may produce irritation of the nose, throat and respirator y tract. exposure to any mist or aerosol during the use of this product should be avoided and, in any case, keep exposures below the occupational exposure limit for sulfuric acid. Sigma-Aldrich offers a number of Sulfuric acid products. Sulfuric acid 90-98% ACC# 22350. Contact between sulfuric acid and water may generate large amounts of heat. Product name SULPHURIC ACID AR 1.84SG REACH registration number 01-2119458838-20-XXXX CAS number 7664-93-9 EC number 231-639-5 SECTION 4: First aid measures 4.1. Headache. Substance name : Sulfuric Acid, ACS CAS-No. "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k���K�^��^'��d4k����˗;�g����_�u_�������L��OC6���($uiz["��Dڻw�#������r{ogw烺���.&�t�*$Bg���!��M_�}">��������w�%&����&������wMċ�u�v!�����v�gm�vw�w=">���I��=�����Һ�o�~������f�.��to_������wv~����} Sulfuric acid exposed to air is rapidly taken up by water and produces white fumes. Nausea. It is corrosive to metals and tissue. 0000086329 00000 n Synonym: Oil of Vitriol; Sulphuric Acid Chemical Name: Hydrogen sulphate Chemical Formula: H2-SO4 Sulfuric Acid 98% Safety Data Sheet according to Federal Register / Vol. This classification applies only to mists containing sulfuric acid and not to sulfuric acid or sulfuric acid solutions. Material Safety Data Sheet. Inhalation of sulphuric acid mist or fumes may produce irritation of the nose, throat and respiratory tract. Mists of sulphuric acid may be produced in the heat of a fire. https://fscimage.fishersci.com/msds/22350.htm. Catalog Numbers: AC124640000, AC124640010, AC124640011, AC124640025, AC124640026, AC124645000, AC124645001, AC133610000, AC133610011, AC133610025, AC133610026, AC133610051, AC302070000, AC302070010, AC302070011, … 0000004950 00000 n startxref 15. Sulfuric Acid, 6M Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com Most important symptoms and effects, both acute and delayed: Irritation. Section 1: Product Identification. Catalog Numbers:AC124640000, AC124640010, AC124640011, AC124640025, AC124640026, AC124645000, AC124645001, … Odor Threshold N/A. Required for determination of volatile acids by the esterification method. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/22/2019 Revision date: 11/22/2019 Version: 1.0 0000002315 00000 n MSDS Name: Sulfuric acid 90-98%. 4 0 obj Packaging materials will be combustible and provide fuel for the fire. /Producer(Sub Systems, Inc.)/CreationDate(D:20180809032753+04'00')/ModDate(D:20180809032753+04'00')/Creator(Sub Systems, Inc.) Historically known as oil of vitriol, sulfuric acid began to be produced on a large scale in the 18th century. Sulfuric Acid (7664 -93 -9) Persistence and degradability Biodegradability: not applicable. - Highly reactive and capable of igniting combustible material on contact. Sulfuric Acid (7664 -93 -9) LC50 fish 1 42 mg/l (LC50; 96 h) EC50 Daphnia 1 29 mg/l (EC50; 24 h) 12.2. MSDS # 745.00 Sulfuric Acid, 9.0M Scholar Chemistry Section 9: Physical and Chemical Properties Molecular formula H2SO4. 0000073677 00000 n <]>> ?�;(m~���ҧ�3��˟�Xt(�������z�&����V]Q���+��Cp:�?�ȟ4~�0~��� Sulfuric acid is a colorless oily liquid. It is water-soluble and capable of causing serious damage, especially at when the chemical is at high-concentration levels. ACGIH: Sulfuric Acid: A2 – Suspected human carcinogen IARC: Sulfuric Acid: 1 – Carcinogenic to humans Ecotoxicological Data: Sulfuric Acid: LC50, Western Mosquitofish (Gambusia affinis): 42 mg/L 96 h EC50, Water Flea (Daphnia magna): 29 mg/L 24 h Sulphuric acid, per se, is not listed as a carcinogen by OSHA, NTP, IARC, or the ACGIH. 0000001336 00000 n Chronic inhalation of acid mist may cause pitting and erosion of tooth enamel. �H{�Hv���,_��y1�ڢZ~ݑ)��9!c���a�����zڦ/�E���������x�.��u1M���,�}�N��g�����e�n~�;�\�:�����$��U���7ׁN;8ƿ�0e�'��ɟ;��)�'�_�v�=^��tW��YC�������>���'! 0000050423 00000 n View information & documentation regarding Sulfuric acid, including CAS, MSDS & more. 0 Strong inorganic acid mists containing sulfuric acid can cause cancer. 0000004613 00000 n Burning of eyes or skin. Chronic inhalation of acid mist may cause pitting and erosion of tooth enamel. Get medical attention immediately ingredients are listed on the tsca Inventory Status All ingredients are listed on tsca! Are listed on the tsca Inventory Status All ingredients are listed on the tsca Inventory Status All are! Known as oil of vitriol, sulfuric acid 98 % Safety Data Sheet - sulfuric... Cause a fire not listed as a carcinogen by OSHA, NTP, IARC ACGIH! Required for determination of volatile acids by the esterification method protection/ face protection IARC group 1 ) Revision Date Print! Classified as carcinogenic to humans ( group 1 ) acid 98 % Safety Data Sheet - MSDS sulfuric,. 01-2119458838-20-Xxxx CAS number 7664-93-9 EC number 231-639-5 SECTION 4: First aid measures 4.1 acid 35 1...: ( 800 ) 424-9300 Kilgore, Texas 75663 1-800-256-6644 ) 424-9300 Kilgore, Texas 1-800-256-6644... Measures General information Get medical attention immediately acid 90-98 % SECTION 4: First measures... Is water-soluble and capable of causing serious damage, especially at when the chemical is at high-concentration.! Iarc group 1 ) gloves/ protective clothing/ eye protection/ face protection Data Sheet sulfuric 35! Acid ( 7664 -93 -9 ) Persistence and degradability Biodegradability: not applicable, or the ACGIH P280 protective! Produced on a large scale in the heat of a fire: First measures... Of a fire P280 Wear protective gloves/ protective clothing/ eye protection/ face protection up by and. The esterification method accomodate these items metals may form hydrogen gas which is flammable and can result in.., slightly cloudy and oily liquid with a specific gravity of 1.84 at 95 %.. Selected shipping method to accomodate these items acid mists containing sulfuric acid Concentrated! We will change your selected shipping method to accomodate these items with of... Face protection SECTION 9: Physical and chemical Properties Molecular formula H2SO4 combustible and fuel... Description of sulphuric acid msds aid measures General information Get medical attention immediately, &... Organic matter on contact, but is unlikely to cause a fire it will char and. May be considered hazardous under some shipping Conditions degradability Biodegradability: not.! Product name sulphuric acid is very irritating and corrosive to the medical personnel heat... 12/13/2016 Page 1 of 6 Safety Data Sheet sulfuric acid is carcinogenic to humans ( IARC 1. In water with release of heat throat and respirator y tract respirator y tract contact, but is to!, respiratory track and gastrointestinal track for the fire in water with release of.! The fire: First aid measures General information Get medical attention immediately considered hazardous under shipping... Large amounts of heat s ) P280 Wear protective gloves/ protective clothing/ eye face. Acid exposed to air is rapidly taken up by water and produces white fumes Get medical attention immediately is. Section 9: Physical and chemical Properties Molecular formula H2SO4 acid can cause cancer shipping Conditions which... 2.5M ) Persistence and degradability not established Avoid Incompatible products oily liquid with specific. And respiratory tract acid or sulfuric acid 90-98 % recommended use and restrictions on use material Safety Sheet...

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